What is Hard Anodizing?

two difference anodizing color on cnc milling components

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What is the Hard Anodizing Process?

Hard anodizing, or Type III anodizing, is an electrochemical process that creates a thick and rigid layer of aluminum oxide on the surface of aluminum parts, which isn’t just any layer. It’s a superhero cape for aluminum, giving it super strength and durability.

How Does the Hard Anodizing Process Work?

The hard coat anodizing process involves immersing the aluminum part in a sulfuric acid bath, typically at a higher concentration than in regular anodizing. 

The bath is cooled to near the freezing point of water to slow down the reaction. 

An electric current, often measured in amps per square foot, is passed through the bath. 

This current increases substantially compared to regular anodizing, causing the aluminum to oxidize and forming a thick, hard anodic coating.

The process starts with the aluminum part washing and then placed into a sulfuric acid bath. Passing an electric current through the bath, causing the aluminum to oxidize and form a layer of aluminum oxide. 

It isn’t a quick dip in the pool, though. The part is left in the bath for a more extended period and at a lower temperature than regular anodizing, and the electric current is much higher. 

This results in a much thicker and harder coating, typically between 0.001 and 0.003 inches thick.

two difference color on a metal miliing parts

Why Hard Anodized Aluminum Special?

But what makes this layer so unique? Aluminum oxide is one of the most complex substances known to man.

 It’s right up there with a diamond on the hardness scale, which means hard anodized aluminum is incredibly wear-resistant and can withstand high-stress levels. 

It’s also highly corrosion-resistant, thanks to the dense, non-porous nature of the anodic coating.

Hard anodizing, or hard coat anodizing, is a unique process that creates a dense anodic coating on aluminum surfaces. 

This coating is not just a superficial layer; it’s a thick, hard aluminum oxide coating that increases aluminum’s hardness and wear resistance.

 

black oxide coating metal bracket

What Does Hard Anodizing Create?

Hard anodizing creates a hard anodic coating that is much thicker and harder than the natural oxide layers on aluminum. 

This coating is typically dark gray to bronze gray, providing excellent abrasion and corrosion resistance. The coating thickness can vary, typically between 0.001 and 0.003 inches.

pink and blue anodizing colors

How Does Hard Anodizing Compare to Regular Anodizing?

While both hard anodizing and regular anodizing involve the formation of an aluminum oxide layer, the processes and results are different. 

Regular anodizing, or Type II anodizing, is done at a higher temperature and for a shorter time than hard anodizing. The resulting coating is thinner and not as hard or wear-resistant as a hard anodized coating.

How does Hard Anodizing Differ Between Regular Anodizing?

In terms of hardness, a hard anodized coating can reach up to 60 on the Rockwell C scale, while a regular anodized coating typically measures around 50. This might not seem like a big difference, but it’s significant in materials science.

 

When it comes to wearing resistance, hard anodizing shines. The thick, hard coating stands up to wear much better than a regular anodized coating. It’s like the difference between wearing a leather jacket and a suit of armor.

 

Corrosion resistance is another area where hard anodizing excels. The dense, non-porous nature of the hard anodized coating makes it an excellent barrier against corrosion. 

Regular anodized coatings also offer good corrosion resistance, but they can’t quite match the performance of hard anodizing.

Anodize Aluminium, different color

What is the Difference in the Anodizing Process?

Regular anodizing, also called Type II anodizing, is done at a higher temperature and for a shorter time than hard anodizing. 

The resulting anodic layer is thinner and not as hard or wear-resistant as a hard anodized coating. The sulfuric acid concentration is typically lower in regular anodizing, and the electric current is not increased as substantially as in hard anodizing.

What is the Difference in the Resulting Coating?

The hard anodizing process, also called hard coat anodizing or Type III anodizing, creates a much thicker and harder coating. 

This hard anodic coating is incredibly wear-resistant and can withstand high-stress levels. It’s also highly corrosion-resistant, thanks to the dense, non-porous nature of the anodic coating.

orange painting supporting metal bracket

What are the Benefits of Hard Anodizing?

Hard anodizing offers several benefits, making it a popular choice for industrial or commercial applications where durability and resistance to wear are essential.

aluminum component anodizing with yellow color

What are the Wear and Corrosion Resistance Benefits?

The hard anodic coating created by hard anodizing is incredibly resistant to wear and corrosion. 

This is due to the hardness of the coating, which can reach up to 60 on the Rockwell C scale, and its dense, non-porous structure. 

This makes hard anodized aluminum parts ideal for applications subject to harsh conditions or heavy use.

What are the Thermal Insulation Benefits?

In addition to its wear and corrosion resistance, the hard anodic coating also provides excellent thermal insulation. 

This is because the aluminum oxide layer created by hard anodizing is a poor conductor of heat. This makes hard anodized parts ideal for high-temperature applications.

u bracket, anodized, blue, sheet metal

What are the Aesthetic Benefits?

Hard anodizing can also have aesthetic benefits. The process can produce a range of colors, from dark gray to a more bronze gray color, depending on the specific process and aluminum alloy used. 

This allows manufacturers to create parts with a durable, attractive finish that can withstand the rigors of use.

colorful fine alum anodizing parts in line on table

What are the Applications of Hard Anodizing?

Hard anodizing has various industrial and commercial applications due to its superior wear and corrosion resistance.

Where is Hard Anodizing Used?

Hard anodized aluminum parts find application in various applications, including engine cylinder heads, where wear-resistant surfaces and high surface hardness are crucial. The abrasion resistance of the hard anodic coating also makes it ideal for use in parts exposed to high friction levels.

pink, anodizing titanium plate

How does hard anodizing benefit these applications?

In these applications, the hard anodized coating protects that regular anodized aluminum or untreated aluminum alloys cannot match. The undyed coating won’t fade or change color over time, even when exposed to high temperatures or harsh conditions.

metal polished

What is the MIL-A-8625 Type III Specification?

The MIL-A-8625 Type III specification is a U.S. military specification for hard anodizing. It specifies the anodic coating’s thickness, hardness, and other properties. Parts anodized according to this specification are often used in military and aerospace applications, where they are exposed to extreme conditions and need excellent wear and corrosion resistance.

aluminum and stainless steel

How is the MIL-A-8625 Type III Specification Achieved?

Anodizing to MIL-A-8625 Type III requires precise control of the sulfuric acid concentration, bath temperature, and electric current. SParts are filled with nickel acetate or fluoride to improve corrosion resistance further after anodizing to increase corrosion resistance.

Wrapping Up: The Power of Hard Anodizing

In conclusion, hard anodizing, or hard coat anodizing, is a robust process that significantly enhances aluminum parts’ hardness, wear, and corrosion resistance. Creating a thick, hard anodic coating transforms aluminum into a super material that can withstand even the harshest conditions. 

Whether used in industrial applications, military equipment, or everyday items, hard anodized aluminum offers durability and performance that’s hard to beat. So, the next time you come across a piece of hard anodized aluminum, remember it’s not just aluminum. It’s aluminum that’s been given the superhero treatment.

shining green anodizing cnc turning part

Frequently Asked Questions

The aluminum hard coat is the hard anodic coating created by the hard anodizing process. It is tough and resistant to wear and corrosion, making it ideal for various applications.

Hard anodizing, also known as hard anodize, is a process that creates a thick, hard anodic coating on the surface of aluminum parts. This coating significantly enhances the parts’ hardness, wear, and corrosion resistance.

The hard anodic coating is created by immersing the aluminum part in a bath of typically high-concentration sulfuric acid and passing an electric current through the bath. The current increases substantially compared to regular anodizing, causing the aluminum to oxidize and forming a thick aluminum oxide coating.

The coatings created by hard anodizing are typically much thicker than those created by regular anodizing. Depending on the specific process and conditions, they can range from 0.001 to 0.003 inches thick.

Hard anodized aluminum is highly abrasion resistant, thanks to the hardness and density of the anodic coating. This makes it ideal for applications that expose the parts to high friction or wear.

The oxide film in hard anodizing is the layer of aluminum oxide formed on the part’s surface. This film is incredibly hard and provides excellent protection against wear and corrosion.

In hard anodizing, the electric current increases substantially compared to regular anodizing, creating a thicker and harder anodic coating. This is often measured in amps per square foot and requires precise control to achieve the desired results.

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